By all means while it's opened up take a shop vac to it and get all that out of there, it reduces the volume of your engine's cooling passages and seen I've plenty of small PWC and outboard engines damaged when that gunk stops up a passageway.
You'll see people recommending that garbage (-50 RV/Marine waterline antifreeze) to winterize motors all the time, even right here on this website. It's not formulated or safe for use in aluminum engines or any inboard or I/O iron block and you may have some damage because of it, can't even begin to tell you how many boats came into my shop over the years with broken blocks, heads etc. and there sit the empty jugs in the boat of -50* pink RV they used last fall to try and save a buck.
Read the label on any container of -50* waterline antifreeze and there will be a warning to bypass the water heater in the boat or rv, but they don't elaborate as to why. Fill a water heater with that stuff and you're buying a new one next season.
The non toxic propylene glycol formulations made for engine use all carry -100* labeling and specifically state safe for use in aluminum engines and don't contain any alcohol or corrosive substances. The confusion is essentially comparing the labeling between old school ethylene glycol used in automotive applications versus non toxic propylene, all propylene container labeling is listed as the burst rating for a copper pipe and they solidify at temperatures well above their degree listing unlike traditional ethylene glycol.
Non toxic -50* water line antifreeze formulations are not all the same, you'll find different concentrations of propylene, alcohol and other substances corrosive to aluminum by manufacturer and some of it literally eats away at aluminum while it sits over the winter.
Regarding your leak, there may be some damage on that head from having used it, clean everything up really well and inspect it closely for cracks or damage I suspect the hole around the head bolt is cracked on an edge.